WebMay 30, 2016 · The isostructural materials, CROFOUR-1-Ni and CROFOUR-2-Ni, are coordination networks that have coordinatively saturated metal centers and two distinct types of micropores, one of which is lined by CrO4 (2-) (CROFOUR) anions and the other is decorated by the functionalized organic linker. These nets offer unprecedented selectivity … WebKroff Inc. One North Shore Center, Suite 450 12 Federal Street Pittsburgh, PA 15212. 412.321.9800. 412.321.9802 (f)

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WebThe Q st values for MOOFOUR-1-Ni and CROFOUR-1-Ni were calculated according to virial equation using the fitted adsorption isotherms at two temperatures (273 K and 298 K) and at three different temperatures (273 K, 283 K and 298 K). Figure S9. CO 2 adsorption … WebMay 30, 2016 · Graphical Abstract. Try HUMming this: An underexplored class of porous materials called hybrid ultra-microporous materials (HUMs) affords new benchmark selectivity for Xe separation from Xe/Kr mixtures. They have two distinct types of … praetorians online

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WebDec 5, 2012 · These MOMs have been assigned RCSR code mmo and are uninodal 6-connected nets. [Ni(bpe)(2)(MoO(4))], MOOFOUR-1-Ni, and its chromate analogue, CROFOUR-1-Ni, exhibit high CO(2) affinity and selectivity, especially at low loading. WebJun 15, 2024 · At 298 K and 1 bar, the Xe uptake of 4.95 mmol/g is significantly higher than most well-known MOF materials under the same conditions, such as MOF-Cu-H (3.19 mmol/g) , squarate-based MOF Co 3 (C 4 O 4) 2 (OH) 2 (1.35 mmol/g) , CROFOUR-1-Ni … WebFor example, the xenon uptakes of HKUST-1 and Ni-MOF-74 with open metal sites could achieve 3.2 mmol g −1 and 4.23 mmol g −1 at room temperature and ambient pressure, ... Actually, the adsorption heat of Xe has a certain advantage over many excellent MOFs, such as CROFOUR-1-Ni (37.4 kJ mol −1), Al-CDC (34.9 kJ mol −1), ... praetorium of pilate